Tool
Treatment Extends Core and Pin Life in Die Cast Operations
by
Dr. Tohru Arai, Technical Advisor
(Reprinted with permission
from Die Casting Engineer, March/April 1999
issue.)
Producing intricate shapes quickly with excellent
precision and good surface quality at a low cost is one of the advantages
of die casting. But, maintaining this advantage is difficult. A
die casting die can cost more than the machine that operates the
die. Die casting is hard on dies and die components and pulling
the dies and pins for repair and/or to polish them is costly.
To help maintain the advantages of die casting and
production up time, die life needs to be extended by reducing repairs.
A tool treatment process called thermal diffusion (TD) can help
die casters reduce maintenance and repairs and extend core and core
pin life.
The TD process prolongs die life by decreasing the
damage caused by thermal and mechanical cyclic loadings and the
reaction with active cast materials that severely damage dies and
die components. It reduces the soldering, corrosion, erosion, wash-out,
wear and heat checking from the loadings and reactions with other
materials. It also provides excellent peel and adhesion strength.
Die life is significantly extended and repairs and polishing are
reduced.
The process also helps protect aluminum die casting
dies which are especially vulnerable to die casting problems.
One of the reasons it works effectively in die cast
operations is found in the process itself. During the treatment
process, the substrate surface of the core and core pins is modified,
creating a metallurgically bonded non-porous vanadium carbide (VC)
layer.
| 
Fig.
1 and 2. Core die used in automotive related
ports production which has been treated with the TD tool treatment
process. Only certain portions of core dies require treatment. |
The VC layer is infused into and onto the dies and
die components (Fig. 1 & 2). This VC layer is .0001- to .0006-inch
thick and has a hardness of 3200 Vickers at room temperature.
Even under the high working temperatures used in
die casting, the VC layer retains its hardness level. And, once
the die is cooled to room temperature, the original hardness of
VC is restored to previous levels.
For example, at 800° Centigrade, the hardness
of the VC layer drops to approximately 900 Vickers, which is still
above the hardness of other treated surfaces. As the VC layer cools
to room temperature, it returns to near its original hardness of
3200 Vickers. Its ability to maintain its hardness under high temperature
applications allows it to perform well in casting operations.
The process also is effective in die cast operations
because the hardness of the VC layer is higher than abrasives such
as aluminum oxide, which is found in hone stones and sandpaper used
for polishing cores and pins. This allows any aluminum that mechanically
sticks to a pin to be easily removed without significant damage
or dimensional change to the pin. Polishing time and the resultant
wear on the pin are greatly reduced.
Another reason it is effective in die cast operations
is that it does not react chemically with aluminum. It protects
dies from the aggressive nature of aluminum and prevents the chemical
interaction between the casting alloy and the die. Therefore, corrosion
and soldering are reduced. With approximately 75% of die cast parts
being produced from aluminum, the process can make a significant
difference in other die cast operations utilizing zinc and magnesium.
The TD process is not widely used in die cast operations
in the United States. Typically, casters do not use tool treatments
at all, although a limited number have begun trial tests.
Japanese and European die casters do use tool treatments
and have been using the process for many years with excellent results.
In Britain, zinc die casters are also using it. (British results
were published in Die Casting Engineer.)1
What is TD?
Developed in Japan in 1969 at the Toyota Central
Research and Development Laboratories, Inc. by Dr. Tohru Arai,
the TD process is a high-temperature tool treatment. During
the process a nonporous metallurgically bonded vanadium carbide
(VC) layer is diffused into and onto tooling substrate. The
VC layer is .0001- to .0006-inch thick and has a hardness
of 3,200 to 3,800 on the Vickers hardness scale. The VC layer
retains its hardness under high temperature working conditions
like die casting.
Because the VC layer is diffused into and
onto the tool substrate, it significantly reduces wear, soldering
and corrosion and provides superior peel strength and adhesion
strength. It extends the life and performance of core pins,
dies, punches and tooling by 5 to 50 times and more.
The process is effective with air-hardening
cold and hot working die steels such as A2, D2 and H13, high
speed steels and cemented carbides. The steels should have
a .2 percent or greater carbon content.
|
In Japan,
the treatment process has been shown to be especially effective
with conventional hot working die steels such as H13, a tool steel
typically used to make die cores and core pins (see Fig. 3). Damages
caused by die casting were significantly reduced. The results from
European die casters tooling treatment have been detailed in several
European pulblications as well as Die Casting Engineer.2

Fig.
3. Core die which has been treated with the process.
By using
treated tooling, the Japanese also realized other benefits. They
reduced interruptions in the produciton process, helping to eliminate
the reconditioning of the casting condition. This reduced cast scrap
and energy usage.
The surface
quality and dimensional accuracy of cast products were also improved.
Using the treatment process meant less sticking of cast materials
on pins. The improved surface quality and dimensional stability
of the cored surfaces also allowed thread tools to last longer.
With the
use of the tooling treatment process, the Japanese also reduced
the casting distortion caused by excessive stresses in ejection
of cast producs. And, finally, the life of tools was increased.
Today,
in Japan, over 8000 pins, insert cores and other die casting components
are treated each month, Japanese die cast plants based in the USA
also use the treatment process.
In the
United States, when die casters do use a tool treatment to help
reduce die wear, it is typically nitriding, a tool surface treatment.
In comparison tests and long term usage tests with nitriding and
TD in casting operations, TD was shown to be more effective than
nitriding (Fig. 4).

Fig.
4. Comparison tests between nitriding and TD show that
TD significantly increases pin life.
| Where
TD Can be Used in Die Cast Operations |
| Core
dies
Pins in zinc die casting
Ejector pins and bushings |
Core
pins
Core
inserts
Sprue bushings |
The process also significantly reduced the number
of pins abandoned per machine and the time required to polish pins
with and without die reset. In comparison with conventional nitriding,
the process significantly extended core pin life, decreased pin
maintenance costs and improved the surface quality of the end product.
In a field test between 1972 and 1979, a Japanese
company completely replaced nitriding with the process. During this
time period, the company increased the total number of castings
produced by 90%, reduced the time spent on die repair work by 80%,
and increased pin life an average of 4 times by using the process
(Table 1 and 2). Profits were increased as well, since downtime
was reduced.
Table
1. Results from a field test conducted by a Japanese company
between 1972 and 1979. In the test, the company completely replaced
nitriding with the tool treatment process.
| Quantity
of machines 1972 = 10, 1979 = 16 |
Ratio |
| Surface
treatment on core pins |
Nitriding |
TD
VC Coating |
| Number
of cast products produced |
100
: 190 |
| Life of
pins |
100
: 417 |
| Number
of core pins abandoned, per a machines |
100
: 28 |
| Frequency
of repair works for pins, accompanied with die reset, per a
machine |
100
: 41 |
| Time required
for repair work for pin accompanied with die reset, per a machine |
100
: 22 |
| Time required
for polishing of pins during casting without die reset, per
a machine |
100
: 25 |
| Time required
for polishing of pins on a day, per a machine |
100
: 25 |
Table
2. Test results between nitriding and the TD process show
that TD increases pin life and significantly reduces polishing time
and the number of pins abandoned in comparison to nitriding.
| |
1972* |
1979* |
| Type
of surface treatment |
S/B
nitriding |
S/B
TD VC |
| Number
of casting machines |
10 |
16 |
| Pin
life (shots) |
2,000
- 50,000
x = 12, 000 |
10,000
- 150,000
x = 50,000 |
| Number
of pins abandoned / machine |
1,040
/ yr. |
290
/ yr. |
| Time
requred to polish pins with die reset / machine |
56.5
hrs. / mo. |
12.5
hrs. / mo. |
| Time
required to polish pins with out die reset / machine |
115.8
hrs. / mo. |
29.0
hrs. / mo. |
| Polishing
time |
30
min. / day |
7.5
min. / day |
* Numbers
per machine
Test results from an American die caster show the
same results. Prior to using the process, the company pulled a core
die every 4 hours to clean the soldered material. Each cleaning
took an average of 30 minutes. This meant one hour of lost production
time for every eight hour shift. The use of treated core pins completely
eliminated the need for periodic cleaning of the core.
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Benefits from Using TD
- Improves
pin life 10 times or more by reducing corrosion and erosion
damage which can cause pin breakage
during cast ejection.
- Reduces
polishing work which can damage pin surface.
- Increases
casting shots several to ten times or more in comparison
to polishing to remove stuck aluminum.
- Drastically
reduces cleaning operations to remove pickup.
- Decreases
die repair work and soldering since it reduces the tendency
of aluminum to mechanically attach to die surface. When
soldering occurs, adhesions can easily be removed by polishing
with a scotch-brite pad or emery paper without taking die
sets out of production.
|
The tests further showed that by treating only one
die, the company increased die life by more than 10 times and realized
more than $20,000 in savings by reducing downtime and labor to clean
dies. The treatment cost less than 10% of the savings realized by
the company, making it an economically viable solution to die wear
problems.
The process can work for United States die casters,
too. It can extend die life, reduce maintenance, polishing and repairs.
References
- Ford,
Eric, Special Coatings Improve Die and Mold Performance, DIE CASTING
ENGINEER, Sept./Oct. 1990, p. 36.
- Arai,
T., "Research and Applications ot Carbide and Nitride Coatings
onto Aluminum Die Casting Molds in Japan," NADCA Transactians,
T95-102, p. 327.
This
article, Tool Treatment Extends Core and Pin Life in Die Cast
Operations was originally published and copyrighted in 1999
by the North American Die Casting Association (NADCA) in Die
Casting Engineer, in March/April 1999. It is published
here with the permission of NADCA and may only be republished
with the permission of NADCA by contacting dce@diecasting.org.
NADCA is the worldwide leader in stimulating growth and improvement
in the die casting industry.
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